Year 2021
382. Copper-Catalyzed Hydroformylation and Hydroxymethylation of Styrenes
Hui-Qing Geng, Tim Meyer, Robert Franke, Xiao-Feng Wu*
Chem. Sci. 2021, 12, 14937-14943.
381. Transition-metal-catalyzed carbonylative cross-coupling with alkyl carbon nucleophiles (Invited review)
Jian-Xing Xu, Chang-Sheng Kuai, Bo Chen, Xiao-Feng Wu*
Chem Catal. 2021, 2, DOI: 10.1016/j.checat.2021.10.023.
380. Nickel-Catalyzed Reductive Aminocarbonylation of Vinyl Triflates with Nitro Compounds for the Synthesis of α,β-Unsaturated Amides
Yong-Wang Huo, Lingyun Yao, Xinxin Qi,* Xiao-Feng Wu*
Org. Chem. Front. 2021, 8, 6974-6978.
379. Copper-Catalyzed 1,2-Trifluoromethylation Carbonylation of Unactivated Alkenes: Efficient Access to β-Trifluoromethylated Aliphatic
Carboxylic Acid Derivatives
Fu-Peng Wu, Yang Yuan, Xiao-Feng Wu*
Angew. Chem. Int. Ed. 2021, 60, 25787-25792.
378. Copper-Catalyzed Alkoxycarbonylation of Alkyl Iodides for the Synthesis of Aliphatic Esters: Hydrogen Makes the Difference
Hui-Qing Geng, Xiao-Feng Wu*
Org. Lett. 2021, 23, 8062-8066.
377. Oxidative Cyclization of Trifluoroacetimidohydrazides with D‑Glucose for the Metal-free Synthesis of 3-Trifluoromethyl-1,2,4-triazoles
Shu-Ning Lu, Hefei Yang, Jiajun Zhang, Zhengkai Chen,* Xiao-Feng Wu*
Adv. Synth. Catal. 2021, 363, 4982-4987.
376. Nickel-Catalyzed Cascade Carbonylative Synthesis of N-Benzoyl Indoles from 2-Nitroalkynes and Aryl Iodides
Lingyun Yao, Jun Ying,* Xiao-Feng Wu*
Org. Chem. Front. 2021, 8, 6541-6545.
375. Palladium-Catalyzed Carbonylative Four-Component Synthesis of β-Perfluoroalkyl Amides
Youcan Zhang, Hui-Qing Geng, Xiao-Feng Wu*
Chem. Eur. J. 2021, 27, 17682-17687.
374. Elemental Sulfur and Dimethyl Sulfoxide-Promoted Oxidative Cyclization of Trifluoroacetimidohydrazides with Methylhetarenes for the
Synthesis of 3-trifluoromethyl-1,2,4-triazoles
Jiajun Zhang, Jianhua Tang, Zhengkai Chen,* Xiao-Feng Wu*
Chin. J. Chem. 2021, 39, 3443-3447.
373. Copper-Catalyzed Borofunctionalization of Styrenes with B2pin2 and CO
Yang Yuan, Fu-Peng Wu, Xiao-Feng Wu*
Chem. Sci. 2021, 12, 13777-13781.
372. Palladium-Catalyzed Perfluoroalkylative Carbonylation of Unactivated Alkenes: Access to β-Perfluoroalkyl Esters
Youcan Zhang, Hui-Qing Geng, Xiao-Feng Wu*
Angew. Chem. Int. Ed. 2021, 60, 24292-24298.
371. Palladium-Catalyzed Carbonylative Synthesis of 5-Trifluoromethyl-1,2,4-triazoles from Trifluoroacetimidohydrazides and Aryl Iodides
Jianhua Tang, Jiajun Zhang, Yu Zhang, Zhengkai Chen*, Xiao-Feng Wu*
Org. Chem. Front. 2021, 8, 6089-6094.
370. Copper-Catalyzed Enantioselective Carbonylation Toward α-Chiral Secondary Amides
Yang Yuan, Fengqian Zhao, Xiao-Feng Wu*
Chem. Sci., 2021, 12, 12676-12681.
369. Nickel-Catalyzed One-Pot Carbonylative Synthesis of 2-Mono- and 2,3-Disubstituted Thiochromenones from 2-Bormobenzenesulfonyl
Chlorides and Alkynes
Wei Wang, Zhi-Peng Bao, Xinxin Qi*, Xiao-Feng Wu*
Org. Lett., 2021, 23, 6589-6593.
368. Copper-Mediated [3+2] Cycloaddition of Trifluoroacetimidoyl Chlorides and N‑Isocyanoiminotriphenylphosphorane for the Synthesis of
3-Trifluoromethyl-1,2,4-triazoles
Hefei Yang, Shu-Ning Lu, Yufei Song, Zhengkai Chen*, Xiao-Feng Wu*
Org. Chem. Front. 2021, 8, 5040-5044.
367. Pd/Cu-Catalyzed Amide-Enabled Selectivity-Reversed Borocarbonylation of Unactivated Alkenes
Fu-Peng Wu, Xiao-Feng Wu*
Chem. Sci. 2021, 12, 10341-10346.
366. Cu/Pd-Catalyzed Borocarbonylative Trifunctionalization of Alkynes and Allenes: Synthesis of β-Geminal-Diboryl Ketones
Yang Yuan, Fu-Peng Wu, Anke Spannenberg, Xiao-Feng Wu*
Sci. China. Chem. 2021, in press
365. Metal-free oxidative cyclization of trifluoroacetimidohydrazides with methylhetarenes: a facile access to 3-hetaryl-5-trifluoromethyl-1,2,4-triazoles
Jiajun Zhang, Tian-Hui Xu, Zhengkai Chen*, Xiao-Feng Wu*
Org. Chem. Front. 2021, 8, 4490-4495.
364. C-F Bond Activation under Transition-Metal-Free Conditions (Invited Review)
Han-Jun Ai, Xingxing Ma, Qiuling Song,* Xiao-Feng Wu*
Sci. China Chem. 2021, 64, 1630-1659.
363. Cobalt-Catalyzed Carbonylative Cycloaddition of Substituted Diynes to Access Complexed Polycyclic Compounds
Jian-Shu Wang, Qi Wang, Yiwen Zhu, Qian Gao, Jun Ying*, Xiao-Feng Wu*
Org. Chem. Front. 2021, 8, 4188-4191.
362. Ligand-Controlled Regiodivergent Thiocarbonylation of Alkynes toward Linear and Branched α, β-Unsaturated Thioesters
Han-Jun Ai, Wangyang Lu, Xiao-Feng Wu*
Angew. Chem. Int. Ed. 2021, 60, 17178-17184.
361. Palladium-catalyzed carbonylative synthesis of quinazolines: silane act as better nucleophile than amidine
Jia-Ming Lu, Yong-Wang Huo, Xinxin Qi,* Xiao-Feng Wu*
Mol. Catal. 2021, 509, 111627.
360. Synthesis of 5-trifluoromethyl-1,2,3-triazoles via base-mediated cascade annulation of diazo compounds with trifluoroacetimidoyl chlorides
Hefei Yang, Tian-Hui Xu, Shi-Ning Lu, Zhengkai Chen,* Xiao-Feng Wu*
Org. Chem. Front. 2021, 8, 3440-3445.
359. Synthesis of 5-Trifluoromethyl-1,2,4-triazoles via Metal-free Annulation of Trifluoroacetimidohydrazides and Methyl Ketones
Jiajun Zhang, Jianhua Tang, Zhengkai Chen,* Xiao-Feng Wu*
Adv. Synth. Catal. 2021, 363, 3060-3069.
358. The First Bismuth Self-Mediated Oxidative Carbonylative Coupling Reaction via BiIII/BiV Redox Intermediates
Fengqian Zhao, Xiao-Feng Wu*
J. Catal. 2021, 397, 201-204.
357. Copper-Catalyzed Borylative Methylation of Alkyl Iodides with CO as the C1 Source: Advantaged by Faster Reaction of CuH over CuBpin
Fu-Peng Wu, Xiao-Feng Wu*
Angew. Chem. Int. Ed. 2021, 60, 11730-11734.
356. Palladium-Catalyzed Carbonylative Cyclization of 2-Alkynylanilines and Aryl Iodides to Access N-Acyl Indoles
Lingyun Yao, Yan Shang, Jian-Shu Wang, Ailin Pan, Jun Ying,* Xiao-Feng Wu*
Org. Chem. Front. 2021, 8, 1926-1929.
355. Palladium-Catalyzed 1,2-Amino Carbonylation of 1,3-Dienes with (N-SO2Py)-2-Iodoanilines: 2,3-Dihydroquinolin-4(1H)-ones Synthesis
Jian-Shu Wang, Yi Na, Jun Ying,* Xiao-Feng Wu*
Org. Chem. Front. 2021, 8, 2429-2433.
354. Palladium-Catalyzed Carbonylative Cyclization of Benzyl Chlorides with Anthranils for the Synthesis of 3-Arylquinolin-2(1H)-ones
Jian-Li Liu, Ren-Rui Xu, Wei Wang, Xinxin Qi,* Xiao-Feng Wu*
Org. Biomol. Chem. 2021, 19, 3584-3588.
353. Synthesis of 3H-1,2,4-triazol-3-ones via NiCl2-promoted cascade annulation of hydrazonoyl chlorides and sodium cyanate
Shiying Du, Zuguang Yang, Jianhua Tang, Zhengkai Chen,* Xiao-Feng Wu*
Org. Lett. 2021, 23, 2359-2363.
352.Palladium-Catalyzed Thiocarbonylation of Alkenes Toward Linear Thioesters
Han-Jun Ai, Fengqian Zhao, Hui-Qing Geng, Xiao-Feng Wu*
ACS Catal. 2021, 11, 3614-3619.
351. Palladium-Catalyzed Thiocarbonylation of Benzyl Chlorides with Sulfonyl Chlorides for the Synthesis of Arylacetyl Thioesters
Wei Wang, Xinxin Qi,* Xiao-Feng Wu*
Adv. Synth. Catal. 2021, 363, 2541-2545.
350. Palladium-Catalyzed Carbonylative Synthesis of 1,5-Dihydro-2H-pyrrol-2-ones from Propargyl Amines and Benzyl Chlorides
Zhengjie Le, Yiwen Zhu, Zhi-Peng Bao, Jun Ying*, Xiao-Feng Wu*
Adv. Synth. Catal. 2021, 363, 1878-1881.
349. Pd/Cu-catalyzed Defluorinative Carbonylative Coupling of Aryl Iodides and gem-Difluoroalkenes: Efficient synthesis of α-Fluorochalcones (Hot Paper)
Fu-Peng Wu, Yang Yuan, Jiawang Liu, Xiao-Feng Wu*
Angew. Chem. Int. Ed. 2021, 60, 8818-8822.
348. Visible Light Induced Palladium-Catalyzed Dehydrogenative Carbonylation of Amines to Oxalamides
Tim Meyer, Jabor Rabeah, Angelika Brückner, Xiao-Feng Wu*
Chem. Eur. J. 2021, 27, 5642-5647.
347. A Novel Construction of Acetamides from Rhodium-Catalyzed Aminocarbonylation of DMC with Nitro compounds
Zhi-Peng Bao, Ren-Guan Miao, Xinxin Qi,* Xiao-Feng Wu*
Chem. Commun. 2021, 57, 1955-1958.
346. Palladium-Catalyzed Carbonylative Synthesis of 2-(Trifluoromethyl)quinazolin-4(3H)-ones from Trifluoroacetimidoyl Chlorides and Nitro Compounds
Le-Cheng Wang, Yu Zhang, Zhengkai Chen,* Xiao-Feng Wu*
Adv. Synth. Catal. 2021, 363, 1417-1426.
345. Silver-Mediated [3+2] Cycloaddition of Azomethine Ylides with Trifluoroacetimidoyl Chlorides for the Synthesis of 5-Trifluoromethyl-imidazoles
Hefei Yang, Shu-Ning Lu, Zhengkai Chen,* Xiao-Feng Wu*
J. Org. Chem. 2021, 86, 4361-4370.
344. Palladium-Catalyzed Cascade Carbonylative Synthesis of 1,2,4-Triazol-3-ones from Hydrazonoyl Chlorides and NaN3
Shiying Du, Wei-Feng Wang, Yufei Song, Zhengkai Chen,* Xiao-Feng Wu*
Org. Lett. 2021, 23, 974-978.
343. Cobalt-Catalyzed Direct C-H Carbonylative Synthesis of Free (NH)-Indolo[1,2-a]quinoxalin-6(5H)-ones
Qian Gao, Jia-Ming Lu, Lingyun Yao, Siqi Wang, Jun Ying,* Xiao-Feng Wu*
Org. Lett. 2021, 23, 178-182.
342. Deaminative Carbonylative Thioesterification of Activated Alkylamines with Thiophenols under Transition-Metal-Free Conditions
Fengqian Zhao, Xiao-Feng Wu*
Org. Chem. Front. 2021, 8, 670-675.
341. Palladium-Catalyzed Directing Group Assisted and Regioselectivity Reversed Cyclocarbonylation of Arylallenes with 2-Iodoanilines
Jian-Shu Wang, Lingyun Yao, Jun Ying,* Xiaoling Luo,* Xiao-Feng Wu*
Org. Chem. Front. 2021,8, 792-798.
340. Pincer Ligand Enhanced Rhodium-Catalyzed Carbonylation of Formaldehyde: Direct Ethylene Glycol Production
Tim Meyer, Robert Konrath, Paul C. J. Kamer, Xiao-Feng Wu*
Asian J. Org. Chem. 2021, 10, 245-250.
339. Nickel-Catalyzed Carbonylative Synthesis of Dihydrobenzofurans
Hui-Qing Geng, Wei Wang, Xiao-Feng Wu*
Catal. Commun. 2021,148, 106170.
338. Rhodium-Catalyzed Carbonylative Coupling of Alkyl Halides with Thiols: A Radical Process Faster than Easier Nucleophilic Substitution
Han-Jun Ai, Jabor Rabeah, Angelika Brückner, Xiao-Feng Wu*
Chem. Commun. 2021, 57, 1466-1469.
337. Radical Carbonylation Under Low CO Pressure: Synthesis of Esters from Activated Alkylamines at Transition Metal-Free Conditions
Fengqian Zhao, Han-Jun Ai, Xiao-Feng Wu*
Chin. J. Chem.2021,39, 927-932.
336. Rhodium-Catalyzed Borylative Carbon Monoxide Reduction to gem-Diborylmethane
Jian-Xing Xu, Fu-Peng Wu, Xiao-Feng Wu*
Catal. Commun. 2021,149, 106205.
335. Ligand-Controlled Copper-Catalyzed Regiodivergent Carbonylative Synthesis of α-Amino Ketones and α-Boryl Amides from Imines and Alkyl Iodides
(Hot Paper)
Fu-Peng Wu, Xiao-Feng Wu*
Angew. Chem. Int. Ed. 2021, 60, 695-700.
